Morphological and thermo-mechanical characterization of open-cell spray polyurethane foamed wall insulation modified with cellulose fiber

Mustafa Khazabi, Mohini Sain

Abstract


Open-cell spray polyurethane foam insulation was prepared using soy-based polyol and water as blowing agent. Cellulose fiber was embedded in polymer matrix as reinforcement and the effects of fiber on morphological changes, as well as thermal and mechanical properties of the foam insulation were investigated. The foam was characterized at cellular level by FTIR and SEM and it was demonstrated that incorporation of fiber in open-cell foam insulation altered the foaming structure. Cell density increased and became more homogeneous. Bulk density and compressive strength of the composite foam system were improved. Thermal effectiveness of the composite foam was improved at lower fiber concentration. Moisture permeability was reduced. However,at higher fiber content the reinforcement effect weakened due to agglomeration of fiber.
Key words: Polyurethane; Polyol; Isocyanate; Cellulose fiber; Cross-linking; Urethane; Urea; Hard and soft segments; Open-cell; Composite foam


Keywords


Polyurethane; Polyol; Isocyanate; Cellulose fiber; Cross-linking; Urethane; Urea; Hard and soft segments; Open-cell; Composite foam

Full Text:

PDF

References


[1] Zimmerman, R. L., Humbert, H. H., & Walker, M. (1997). Low-odour amine blowing catalysis in flexible polyether foam. Paper presented at the Seminar Organized by Rapra Technology Ltd., U.K.

[2] Sekkar, V., Gopalakrishnan S., & Ambika Devi, K. (2003). Studies on allophanate-urethane networks based on hydroxyl terminated polybutadiene: Effect of isocyanate type on the network characteristic. European Polymer Journal, 39(6), 1281-1290.

[3] Bagdi, K., Molnar, K., Sajo, I., & Pukanszky, B. (2011).Specific interactions, structure and properties in segmented polyurethane elastomers. eXpress Polymer Letters, 5(5), 417-427.

[4] The Essential Chemical Industry Online. (2014, August 15). Polyurethanes [Online forum comment]. Retrieved from http://www.essentialchemicalindustry.org/polymers/polyurethane.html

[5] Irle, C., Roschu, R., Luehmann, E., & Feng, S. (2002). Waterborne parquet coatings based on crosslinked polyurethane dispersions. Paint & Coatings Industry, 18(2), 28.

[6] Szycher, M. (1999). Szycher’s handbook of polyurethanes. New York, USA: CRC Press.

[7] ASTM International. (2012). ASTM D883-12 Standard Terminology Relating to Plastics. West Conshohocken, USA: ASTM.

[8] Xia, C., Lee, J. L., Widya, T., & Macosko, C. (2005). Polyurethane/clay nanocomposites foams: Processing, structure and properties. Polymer, 46, 775-783.

[9] Ema, Y., Ikeya, M., & Okamoto, M. (2006). Foam processing and cellular structure of polylactide-based nanocomposites. Polymer, 47, 5350-5359.

[10] Ting, L., Liang, M., Fuwei, L., Wuzhou, J., Zhaobo, H., & Pengfei, F. (2011). Preparation, structure, and properties of flexible polyurethane foams filled with fumed silica. Journal of Natural Sciences, 16(1), 29-32.

[11] Gayathri, R., Vasanthakumari, R., & Padmanabhan, C. (2013). Sound absorption, thermal and mechanical behavior of polyurethane foam modified with nano silica, nano clay and crumb rubber fillers. International Journal of Scientific & Engineering Research, 4(5), 301-308.

[12] Vladimir, G. (2010). Testing and application of new phenomenological material model for foam materials [Online forum comment]. Retrived from http://www.posterus.sk/?p=3923

[13] Xiao, C., & Fan, Q. (2008). Effects of crosslinking density on structure and properties of interpenetrating polymer networks from polyurethane and nitroguar gum. Polymer Composites, 29(7), 758-767.

[14] Federation of European Rigid Polyurethane Foam Association. (2006). Thermal Insulation Materials Made of Rigid Polyurethane Foam [Online forum comment]. Retrived from http://www.excellence-in-insulation.eu/site/fileadmin/user_upload/PDF/Thermal_insulation_materials_made_of_rigid_polyurethane_foam.pdf

[15] Matuana, L. M., Park, C. B., & Balatinecz, J. J. (1998). Cell morphology and property relationships of microcellular foamed PVC/Wood-fiber composites. Polym. Eng. Sci., 38(11), 1862-1872.

[16] Mukhopadhyaya, P., Kumaran, K., Lackey, J., & Reenen, D. (2007). Water vapor transmission measurement and significance of corrections. Journal of ASTM International, 8(4), 1-12.

[17] Bismarck, A., Aranberri-Askargorta, I., & Springer, J. (2002). Surface characterization of flax, hemp and cellulose fibers; surface properties and the water uptake behavior. Polymer Composites, 23(5), 872-894.




DOI: http://dx.doi.org/10.3968/6319

Refbacks

  • There are currently no refbacks.


Copyright (c)




Share us to:   


Reminder

  • How to do online submission to another Journal?
  • If you have already registered in Journal A, then how can you submit another article to Journal B? It takes two steps to make it happen:

1. Register yourself in Journal B as an Author

  • Find the journal you want to submit to in CATEGORIES, click on “VIEW JOURNAL”, “Online Submissions”, “GO TO LOGIN” and “Edit My Profile”. Check “Author” on the “Edit Profile” page, then “Save”.

2. Submission

  • Go to “User Home”, and click on “Author” under the name of Journal B. You may start a New Submission by clicking on “CLICK HERE”.

We only use three mailboxes as follows to deal with issues about paper acceptance, payment and submission of electronic versions of our journals to databases:
caooc@hotmail.com; aped@cscanada.net; aped@cscanada.org

 Articles published in Advances in Petroleum Exploration and Development are licensed under Creative Commons Attribution 4.0 (CC-BY)

ADVANCES IN PETROLEUM EXPLORATION AND DEVELOPMENT Editorial Office

Address:1055 Rue Lucien-L'Allier, Unit #772, Montreal, QC H3G 3C4, Canada.

Telephone: 1-514-558 6138
Website: Http://www.cscanada.net
Http://www.cscanada.org
E-mail:office@cscanada.net;  office@cscanada.org

Copyright © 2010 Canadian Research & Development Centre of Sciences and Cultures